Self-sufficient asymmetric reduction of β-ketoesters catalysed by a novel and robust thermophilic alcohol dehydrogenase co-immobilised with NADH
نویسندگان
چکیده
A highly robust and productive self-sufficient heterogeneous biocatalysts to asymmetrically reduce β-ketoesters.
منابع مشابه
Towards an asymmetric organocatalytic α-cyanation of β-ketoesters
This communication describes the first proof of concept for an asymmetric α-cyanation of β-ketoesters using a hypervalent iodine-based electrophilic cyanide-transfer reagent. A series of different organocatalysts has been investigated and it was found that the use of naturally occurring Cinchona alkaloids allows obtaining the target products in good yields and with moderate enantioselectivities...
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We present an easy method for the synthesis of β-ketoesters starting from various carbocyclic and heterocyclic carboxylic acids and esters. The β-ketoester side-chain was introduced by a sequence involving α-deprotonation and quenching with CO2, conversion to the corresponding acid chloride and subsequent chain elongation using deprotonated ethyl acetate.
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ژورنال
عنوان ژورنال: Catalysis Science & Technology
سال: 2021
ISSN: ['2044-4761', '2044-4753']
DOI: https://doi.org/10.1039/d1cy00268f